Including the recommended
if (!defined('CIVICRM_SMARTY_AUTOLOAD_PATH')) {
define('CIVICRM_SMARTY_AUTOLOAD_PATH', $civicrm_root . '/packages/smarty5/Smarty.php');
}
in civicrm.settings.php leads to a fatal error with this extension enabled. Disabling it resolves the error. Old extensions seem to be a common cause for this issue.
I'm on WordPress 6.7.2 and CiviCRM 6.0.1.